張文雄2007年10月從日本理化學研究所回到北京大學化學與分子工程學院有機所工作，任副教授，在席振峰院士課題組開展科研工作，2016年晉升為教授，2017年獲得國家杰出青年科學基金。通過國際評估等程序，2021年1月始，在北京大學化學與分子工程學院無機所建立“稀土金屬有機化學”課題組，任課題組長/PI。本課題組圍繞高活性稀土金屬有機雜環(huán)化合物的合成、結構表征、成鍵模式及對小分子的活化和反應機理開展系列研究：首次實現(xiàn)了稀土金屬雜環(huán)戊二烯的高效合成，在此基礎上首次實現(xiàn)了從白磷出發(fā)直接構建有機膦化合物，為稀土金屬及白磷的高效利用提供了新思路；首次實現(xiàn)了高張力稀土金屬雜環(huán)丙烯的合成和結構表征，發(fā)現(xiàn)其具有休克爾芳香性；成功構建了雙釤雜環(huán)戊烯，首次實現(xiàn)了雙碳負離子型共軛烯烴的還原，揭示該雙碳負離子的p反鍵軌道能夠從能量更高的釤4f軌道接收兩個電子。在已有工作基礎上，擬開展：1）新的稀土金屬有機雜環(huán)的合成，并研究與小分子，如白磷，CO，CO2，氧氣等的反應性和催化活性；探索芳香性稀土金屬有機雜環(huán)的合成和成鍵模式；2）利用金屬有機化學手段，建立簡單、高效的白磷活化方法直接構建有機膦化合物，打破傳統(tǒng)的工業(yè)路線，實現(xiàn)白磷的直接應用。

現(xiàn)課題組誠聘博士后研究人員1-4名，要求在金屬有機化學、或過渡金屬配位化學、或光化學、或電化學研究領域有較好的工作積累，進站后開展稀土金屬有機雜環(huán)化學或白磷的轉化化學研究。

具體待遇等請聯(lián)系：張文雄教授https://www.chem.pku.edu.cn/ktz2/wjhxktzz/125454.htm

電話：010-62758294

電子信箱：wx_zhang@pku.edu.cn，郵件標題注明：應聘博士后+本人姓名 。

代表性論文：

(*: Corresponding author, #: Authors contributed equally)

1.      Yu Zheng,# Chang-Su Cao,# Wangyang Ma,# Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc. 2020, 142, 10705-10714.

2.      Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction, Chem. Soc. Rev. 2020, 49, 5810-5849.

3.      Nan Li,# Botao Wu,# Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction, Angew. Chem. Int. Ed. 2020, 59, 8868-8872.

4.      Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity, J. Am. Chem. Soc. 2019, 141, 20547-20555.

5.      Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation, J. Am. Chem. Soc. 2019, 141, 8773-8777.

6.      Shanshan Du,# Jimin Yang,# Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds, J. Am. Chem. Soc. 2019, 141, 6843-6847.

7.      Jianhao Yin,# Jiapeng Li,# Gao-Xiang Wang,# Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex, J. Am. Chem. Soc. 2019, 141, 4241-4247.

8.      Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes, Angew. Chem. Int. Ed. 2017, 56, 15886-15890.

9.      Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex, Angew. Chem. Int. Ed. 2017, 56, 9188-9192.

10.  Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation, J. Am. Chem. Soc. 2017, 139, 13688-13691.

11.  Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization, J. Am. Chem. Soc. 2017, 139, 5039-5042.

12.  Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes, Chem. Sci. 2017, 8, 6852-6856.

13.  Wangyang Ma,# Chao Yu,# Tianyang Chen,# Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity, Chem. Soc. Rev. 2017, 46, 1160-1192.

14.  Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts, Angew. Chem. Int. Ed. 2016, 55, 14762-14765.

15.  Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus, Angew. Chem. Int. Ed. 2016, 55, 9187-9190.

16.  Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds, Chem. Rev. 2015, 115, 12045-12090.

17.  Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides, J. Am. Chem. Soc. 2012, 134, 2926-2929.

18.  Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis, Acc. Chem. Res. 2011, 44, 541-551.

19.  Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation, Angew. Chem. Int. Ed. 2011, 50, 8122-8126.

20.  Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides, J. Am. Chem. Soc. 2009, 131, 15108-15109.

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